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All lessons Modern Physics24 min

The Atomic Model

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01
Hook
02
Explore
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Formalize
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Practice
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Challenge
Interactive simulation
01

Hook

Astronomers can look at a star 100 light-years away — a star no human will ever visit — and tell you exactly which elements it contains, what temperature it is, and how fast it's moving. They do this by splitting its light into a spectrum and reading a pattern of dark lines. But here is the shocking part: every hydrogen atom in the universe absorbs and emits light at exactly the same wavelengths. Every single one. On Earth, in the Sun, in a galaxy a billion light-years away. How can atoms spread across billions of light-years all 'agree' on the same precise wavelengths to absorb?

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Spoilers

The Atomic Model — summary and key formula

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The question

Astronomers can look at a star 100 light-years away — a star no human will ever visit — and tell you exactly which elements it contains, what temperature it is, and how fast it's moving. They do this by splitting its light into a spectrum and reading a pattern of dark lines. But here is the shocking part: every hydrogen atom in the universe absorbs and emits light at exactly the same wavelengths. Every single one. On Earth, in the Sun, in a galaxy a billion light-years away. How can atoms spread across billions of light-years all 'agree' on the same precise wavelengths to absorb?

The answer is that atomic structure is not a local accident — it is dictated by mathematics. Electrons in atoms can only occupy discrete energy levels, like rungs on a fixed ladder whose rung spacings are determined by quantum mechanics. When light hits an atom, only photons with exactly the right energy (matching an energy gap) are absorbed. This universality is what lets spectroscopy decode the composition of stars — and it's the foundation of every laser, LED, and atomic clock on Earth.

The key idea

Bohr's model: electrons in hydrogen occupy discrete energy levels labelled n = 1, 2, 3, … The energy at each level is E_n = −13.6/n² eV (negative because the electron is bound — work must be done to free it). The ground state n=1 has energy −13.6 eV. When an electron absorbs a photon of exactly the right energy, it jumps to a higher level. When it falls back, it emits a photon with that exact energy difference. No other energies are allowed — hence atoms produce discrete spectral lines, not a continuous rainbow.

The Bohr model works precisely for hydrogen but breaks down for larger atoms. The modern quantum model replaces circular orbits with probability clouds (orbitals) — but the fundamental insight holds: energy in atoms is quantised. Electrons don't spiral inward like a decaying satellite; they teleport between allowed states, emitting or absorbing exactly quantised photons. The ionisation energy — the energy needed to fully remove an electron from level n — is E_ion = 13.6/n² eV. From the ground state this is 13.6 eV, which matches experiment perfectly.

The formula

En=−13.6n2 eVΔE=hfE_n = \dfrac{-13.6}{n^2}\,\text{eV} \qquad \Delta E = hfEn​=n2−13.6​eVΔE=hf
  • ·E_n = energy of level n (electron-volts
  • ·eV)
  • ·n = principal quantum number (1
  • ·2
  • ·3...)
  • ·ΔE = photon energy (eV)
  • ·h = Planck's constant (4.14×10⁻¹⁵ eV·s)
  • ·f = frequency of emitted or absorbed photon (Hz)